【单选题】
至终点,则试样中H2O2的含量为___。M(H2O2)=34.0lg/mol。
A. 2.96%
B. 29.58%
C. 5.92%
D. 59.17%
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相关试题
【单选题】
[2]碘量法测定铜盐中铜的含量,利用的反应为:CuSO4+4I-=2CuI↓+I2 , I2+2Na2S2O3→Na2S4O6+2NaI, 则CuSO4与Na2 S2O3的基本单元的关系是___
A. n(1/4 CuSO4)=n(Na2S2O3)
B. n(1/2 CuSO4)=n(Na2S2O3)
C. n(CuSO4)=n(Na2S2O3)
D. n(1/2CuSO4)=n(1/2Na2S2O3)
【单选题】
[3]水中COD的测定是采用___进行的。
A. 碘量法
B. 重铬酸钾法
C. 溴酸钾法
D. 铈量法
【单选题】
[1]用高锰酸钾法测定硅酸盐样品中Ca2+的含量。称取样品0.5972g,在一定条件下,将Ca2+沉淀为CaC2O4,过滤,洗涤沉淀,将洗涤的CaC2O4溶于稀硫酸中,用c(KMnO4)=0.05052mol/L的KMnO4标准溶液滴定,消耗25.62mL,硅酸盐中Ca的质量分数为 ___。已知M (Ca)=40.08g/mol。
A. 24.19%
B. 21.72%
C. 48.38%
D. 74.60%
【单选题】
[3]间接碘量法中加入淀粉指示剂的适宜时间是___。
A. 滴定开始时
B. 滴定至近终点,溶液呈浅黄色时
C. 滴定至I3-离子的红棕色褪尽,溶液呈无色时
D. 在标准溶液滴定了近50%时
【单选题】
[3]用KMnO4法测定H2O2,滴定必须在___。
A. 中性或弱酸性介质中
B. c( H2SO4)=1mol/L介质中
C. pH=10氨性缓冲溶液中
D. 强碱性介质中
【单选题】
[2]间接碘量法测定水中Cu2+含量,介质的pH值应控制在___。
A. 强酸性
B. 弱酸性
C. 弱碱性
D. 强碱性
【单选题】
[2]配制I2标准溶液时,是将I2溶解在___中。
A. 水
B. KI溶液
C. HC1溶液
D. KOH溶液
【单选题】
[2]当增加反应酸度时,氧化剂的电极电位会增大的是___。
A. Fe3+
B. I2
C. K2Cr2O7
D. Cu2+
【单选题】
[1] MnO4-与Fe2+反应的平衡常数___。已知,。
A. 3.4×10 12
B. 320
C. 3.0×10 62
D. 4.2×10 53
【单选题】
[3]影响氧化还原反应平衡常数的因素是___。
A. 反应物浓度
B. 催化剂
C. 温度
D. 诱导作用
【单选题】
[2]重铬酸钾滴定法测铁,加入H3PO4的作用主要是___。
A. 防止沉淀
B. 提高酸度
C. 降低Fe3/Fe2-电位,使突跃范围增大
D. 防止Fe2+氧化
【单选题】
[2]直揍碘量法应控制的条件是___。
A. 强酸性条件
B. 强碱性条件
C. 中性或弱酸性条件
D. 什么条件都可以
【单选题】
[2]在间接碘量法中,若酸度过强,则会有___产生。
A. SO2
B. S
C. SO2和S
D. H2S
【单选题】
[2]在碘量法中,淀粉是寺属指示剂,当溶液呈蓝色时,这是___。
A. 碘的颜色
B. I-的颜色
C. 游离碘与淀粉生成物的颜色
D. I-与淀粉生成物的颜色
【单选题】
[3]自动催化反应的犄点是反应速率___。
【单选题】
[2]下列几种标准溶液一般采用直接法配制的是___。
A. KMnO4标准溶液
B. I2标准溶液
C. K2Cr2O7标准溶液
D. Na2S2O3标准溶液
【单选题】
[2]下列关于硫酸铈法的说法不正确的是___。
A. 硫酸铈标准溶液可直接配制
B. Ce4+被还原为Ce3+,只有一个电子转移,不生成中间价态产物
C. 在酸度低于Imol/L时,磷酸对测定无干扰
D. 可在盐酸介质中直接滴定Fe2+,Cl-无影响
【单选题】
[2]标定KMnO4时,第1滴加入没有褪色以前,不能加入第2滴,加入几滴后,方可加快滴定速度原因是___。
A. KMnO4自身是指示剂,待有足够KMnO4时才能加快滴定速度
B. O2为该反应催化剂,待有足够氧时才能加快滴定速度
C. Mn2+为该反应催化剂,待有足够Mn2+才能加快滴定速度
D. MnO2为该反应催化剂,待有足够MnO2才能加快滴定速度
【单选题】
[2]软锰矿主要成分是MnO2,测定方法是过量Na2C2O4与试样反应后,用KMnO4标准溶液返滴定过剩的C2O42-,然后求出MnO2含量。不用还原剂标准溶液直接滴定的原因是___。
A. 没有合适还原剂
B. 没有合适指示剂
C. 由于MnO2是难溶物质,直接滴定不适宜
D. 防止其他成分干扰
【单选题】
[2]在酸性介质中,周KMnO4溶液滴定草酸盐溶液时,滴定应___。
A. 像酸碱滴定那样快速进行
B. 始终缓慢地进行
C. 在开始时缓慢,以后逐步加快,近终点时又减慢滴定速度
D. 开始时快,然后减慢
【单选题】
[3]下列氧化还原滴定指示剂属于专属的是___。
A. 二苯胺磺酸钠
B. 次甲基蓝
C. 淀粉溶液
D. 高锰酸钾
【单选题】
Ce4+滴定Fe2+时,最适宜的指示剂为___。
A. 二苯胺磺酸钠(φθ′㏑=0.84V)
B. 邻苯胺基苯甲酸(φθ′㏑=0.89V)
C. 邻二氮菲-亚铁(φθ′㏑=1.06V)
D. 硝基邻二氮菲-亚铁(φθ′㏑=1.25V)
【单选题】
[2]用Na2C2O4标定高锰酸钾中,刚开始时褪色较慢,但之后褪色变快的原因是___。
A. 温度过低
B. 反应进行后,温度升高
C. Mn2+催化作用
D. 高锰酸钾浓度变小
【单选题】
[2]为减小间接碘量法的分析误差,下面哪些方法不适用___。
A. 开始慢摇快滴,终点快摇慢滴
B. 反应时放置于暗处
C. 加入催化剂
D. 在碘量瓶中进行反应和滴定
【单选题】
[2]下列几种标准溶液一般采用直接法配制的是___。
A. KMnO4标准溶液
B. I2标准溶液
C. K2Cr2O7标准溶液
D. Na2S2O3标准溶液
【单选题】
[3]标定Na2S2O3溶液的基准试剂是___。
A. Na2 C2 04
B. (NH4)2C2O4
C. Fe
D. K2CrO7
【单选题】
[2]在酸性介质中,用KMnO4溶液滴定草酸盐溶液,滴定应___。
A. 在室温下进行
B. 将溶液煮沸后即进行
C. 将溶液煮沸,冷至85℃进行
D. 将溶液加热到75~85℃时进行
【单选题】
[2]在能斯特方程式的物理量中,既可能是正值,又可能是负值的是___。
【单选题】
[2]在拟定氧化还原滴定滴定操作中,不属于滴定操作应涉及的问题是___。
A. 滴定速度和摇瓶速度的控制
B. 操作过程中容器的选择和使用
C. 共存干扰物的消除
D. 滴定过程中溶剂的选择
【单选题】
[2]碘量法测定CuSO4含量,试样溶液中加入过量的KI,下列叙述其作用错误的是___。
A. 还原Cu2+为Cu+
B. 防止I2挥发
C. 与Cu+形成CuI沉淀
D. 把CuSO4还原成单质Cu
【单选题】
[2] Pb2+ +Sn=Pb + Sn2+反应,已知EθPb2+/Pb=-0.13V、φθSn2+/Sn= -0.14V,在标准状态下,反应向___进行,当[Pb2+] =0.50mol/L时,反应又向( )进行。
A. 左、左
B. 左、右
C. 右、右
D. 右、左
【判断题】
[2]溶液的酸度越高,KMnO4氧化草酸钠的反应进行得越完全,所以用基准草酸钠标定KMn04溶液时,溶液的酸度越高越好
【判断题】
[2]氧化还原滴定中,影响电势突跃范围大小的主要因素是电对的电势差,而与溶液的浓度几乎无关
【判断题】
ΨCu2+/Cu和ΨFe3+/Fe的值都不变
【判断题】
[2]氧化还原反应次序是电极电位相差最大的两电对先反应
【判断题】
[2]氧化还原反应中,两电对电极电位差值越大,反应速率越快
【判断题】
[3]标定KMnO4溶液的基准试剂是碳酸钠
【判断题】
[2]错KMnO4标准溶液测定MnO2含量,用的是直接滴定法
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We should not ___ ourselves to the classroom. We should go out of the classroom, see the world and talk to others as much as we can.
A. entertain
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I have always been grateful ___ Fred __the generous and helpful information when I was at the crossroads.
A. to … for
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I think we both need to ___ the past, be happy about what we had for a time, learn from our experiences, and move on from there.
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【单选题】
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Because of his long illness, Lee’s English level had dropped, but he was determined to ___ the other students by working harder.
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A. slip down
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A. put out
B. took off
C. pulled over
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A. eager
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In the race, it looked as if he would be the first, but then another young man who was close behind him put on speed and ___ by a few seconds.
A. beat him for it
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【单选题】
It is really helpful to have someone like you that we can ___ and count on during difficult times.
A. lean on
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【单选题】
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A. reserved for
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___ that new homes cost more than older homes, but that is not true across the country anymore.
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Tom tried to justify his absence from the meeting by ___ that he had been ill that day.
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